JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001751
Submitter
The Noguchi Institute
Reaction ID
R-0000-001751
Regist Date
2012/06/21 17:51:09
REACTANT
MOLECULE ID
JCGG-COM0002292 (Reaction Tree)
Skeleton
JCGG-STR032397
Mol
0.020 mol
MOLECULE ID
JCGG-COM0002100
Reactant Type
NaH
Mol
0.115 mol
MOLECULE ID
JCGG-COM0000161
Reactant Type
BnBr
Mol
0.099 mol
PRODUCT
MOLECULE ID
JCGG-COM0002293 (Reaction Tree)
Skeleton
JCGG-STR032397
Yield
94%
REACTION DETAIL
Reaction Time
19 hours
Reaction Temp
NOT specified
Solvent
DMF
COMMENT
Keywords: oligosaccharide synthesis, n-pentenyl glycosides, NPGs, Orthoester Rearrangement
The reaction is the 3rd part of the sequence.
REFERENCE
Reference Id
REF-0000-000196
Source
PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
REF-0000-000197
Source
ISBN 0-8247-9802-3
Reference Id
REF-0000-000236
Source
J. Am. Chem. Soc. 117:1546 (1995)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)