JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001750
Submitter
The Noguchi Institute
Reaction ID
R-0000-001750
Regist Date
2012/06/21 17:51:05
REACTANT
MOLECULE ID
JCGG-COM0002291 (Reaction Tree)
Skeleton
JCGG-STR032397
Mol
0.042 mol
MOLECULE ID
JCGG-COM0000530
Reactant Type
NaOMe
Mol
0.021 mol
PRODUCT
MOLECULE ID
JCGG-COM0002292 (Reaction Tree)
Skeleton
JCGG-STR032397
Yield
95%
REACTION DETAIL
Reaction Time
28 hours
Reaction Temp
NOT specified
Solvent
MeOH/CH2Cl2 = 8/1
COMMENT
Keywords: oligosaccharide synthesis, n-pentenyl glycosides, NPGs, Orthoester Rearrangement
The reaction is the 2nd part of the sequence.
REFERENCE
Reference Id
REF-0000-000196
Source
PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
REF-0000-000197
Source
ISBN 0-8247-9802-3
Reference Id
REF-0000-000236
Source
J. Am. Chem. Soc. 117:1546 (1995)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)