Reaction:JCGG-RAC0001745

JCGG ID		JCGG-RAC0001745
Submitter		The Noguchi Institute
Reaction ID		R-0000-001745
Regist Date		2012/06/21 17:50:34
REACTANT
MOLECULE ID		JCGG-COM0002282 (Reaction Tree)
	Mol	1.6 mmol
MOLECULE ID		JCGG-COM0002283 (Reaction Tree)
	Mol	0.32 mmol
MOLECULE ID		JCGG-COM0000624
	Reactant Type	AgOTf
	Mol	1.6 mmol
MOLECULE ID		JCGG-COM0002263
	Reactant Type	Cp2HfCl2
	Mol	1.6 mmol
MOLECULE ID		JCGG-COM0001346
	Reactant Type	DTBMP
	Mol	0.08 mmol
PRODUCT
MOLECULE ID		JCGG-COM0002284 (Reaction Tree)
	Yield	50%
REACTION DETAIL
Reaction Time		2 hours, 16 hours
Reaction Temp		0 degree C, 25 degree C
Solvent		CH2Cl2, CH2Cl2
Comment		1) +all, 2) temperature change
		MS 4A was included in the solvent.
COMMENT
Keywords: glycosyl fluorides, glycosyl sulfides, NodRm-IV factors
There are multiple steps in this reaction.
36% of starting alcohol (compound 64) was also obtained.
REFERENCE
Reference Id		REF-0000-000196
	Source	PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id		REF-0000-000197
	Source	ISBN 0-8247-9802-3
Reference Id		REF-0000-000233
	Source	J. Am. Chem. Soc. 114:8701 (1992)