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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001736 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001736
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Regist Date |
2012/06/21 17:49:01 | ||||
| REACTANT | |||||
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Mol |
0.20 mmol | ||||
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Reactant Type |
DAST | ||||
Mol |
0.62 mmol | ||||
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Reactant Type |
NBS | ||||
Mol |
0.25 mmol | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
80% | ||||
| REACTION DETAIL | |||||
Reaction Time |
20 minutes, 2 hours | ||||
Reaction Temp |
-78 degree C, -20 degree C | ||||
Solvent |
CH2Cl2, CH2Cl2 | ||||
Comment |
1) +all except NBS, 2) +NBS | ||||
| The reactants were mixed at -78 degree in Celsius, and allowed to warm to -20 degree within the reaction time. (second step) | |||||
| COMMENT | |||||
| Keywords: glycosyl fluorides, glycosyl sulfides, sulfated Lea tetrasaccharide | |||||
| There are multiple steps in this reaction. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000196 | ||||
Source |
PREPARATIVE CARBOHYDRATE CHEMISTRY | ||||
Reference Id |
REF-0000-000197 | ||||
Source |
ISBN 0-8247-9802-3 | ||||
Reference Id |
REF-0000-000229 | ||||
Source |
J. Am. Chem. Soc. 115:8843 (1990) | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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