Reaction:JCGG-RAC0001733

JCGG ID		JCGG-RAC0001733
Submitter		The Noguchi Institute
Reaction ID		R-0000-001733
Regist Date		2012/06/21 17:47:20
REACTANT
MOLECULE ID		JCGG-COM0002261 (Reaction Tree)
	Mol	0.459 mmol
MOLECULE ID		JCGG-COM0002262 (Reaction Tree)
	Mol	0.077 mmol
MOLECULE ID		JCGG-COM0000624
	Reactant Type	AgOTf
	Mol	1.15 mmol
MOLECULE ID		JCGG-COM0002263
	Reactant Type	Cp2HfCl2
	Mol	1.15 mmol
PRODUCT
MOLECULE ID		JCGG-COM0002264 (Reaction Tree)
	Yield	96%
REACTION DETAIL
Reaction Time		4 hours, 1 hour
Reaction Temp		below 5 degree C, room temp
Solvent		CH2Cl2, CH2Cl2
Comment		1) +all, 2) temperature change
		MS 4A was included in the solvent.
		The reactants were mixed at 0 degree in Celsius before stirred at below 5 degree. (first step)
COMMENT
Keywords: glycosyl fluorides, glycosyl sulfides, trimeric Lex
There are multiple steps in this reaction.
REFERENCE
Reference Id		REF-0000-000196
	Source	PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id		REF-0000-000197
	Source	ISBN 0-8247-9802-3
Reference Id		REF-0000-000227
	Source	J. Am. Chem. Soc. 112:3693 (1990)