JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001732
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001732
Regist Date
 2012/06/21 17:46:16
REACTANT
MOLECULE ID
 JCGG-COM0002259 (Reaction Tree)
Mol
 1.07 mmol
MOLECULE ID
 JCGG-COM0002073
Mol
 0.867 mmol
MOLECULE ID
 JCGG-COM0000032
Reactant Type
 AgClO4
Mol
 2.14 mmol
MOLECULE ID
 JCGG-COM0000813
Reactant Type
 SnCl2
Mol
 2.14 mmol
MOLECULE ID
 JCGG-COM0001344
Reactant Type
 2,6-lutidine
Mol
 0.856 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0002260 (Reaction Tree)
Skeleton
JCGG-STR001961
Yield
 92%
REACTION DETAIL
Reaction Time
 4 hours
Reaction Temp
 below 5 degree C
Solvent
 CH2Cl2
Comment
 MS 4A was included in the solvent.
The reactants were mixed at 0 degree in Celsius before stirred at below 5 degree.
The mixture was allowed to warm to room temperature at the end of the reaction.
COMMENT
Keywords: glycosyl fluorides, glycosyl sulfides, trimeric Lex
REFERENCE
Reference Id
 REF-0000-000196
Source
 PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
 REF-0000-000197
Source
 ISBN 0-8247-9802-3
Reference Id
 REF-0000-000227
Source
 J. Am. Chem. Soc. 112:3693 (1990)
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)