JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001731
Submitter
The Noguchi Institute
Reaction ID
R-0000-001731
Regist Date
2012/06/21 17:46:03
REACTANT
MOLECULE ID
JCGG-COM0002257 (Reaction Tree)
Reactant Type
(in 3.5 mL of Et2O)
Mol
0.25 mmol
MOLECULE ID
JCGG-COM0002256 (Reaction Tree)
Reactant Type
(in 3.5 mL of Et2O)
Mol
0.25 mmol
MOLECULE ID
JCGG-COM0000032
Reactant Type
AgClO4
Mol
0.46 mmol
MOLECULE ID
JCGG-COM0000813
Reactant Type
SnCl2
Mol
0.46 mmol
PRODUCT
MOLECULE ID
JCGG-COM0002258 (Reaction Tree)
Yield
66%
REACTION DETAIL
Reaction Time
2 minutes + 2 hours, 10 hours
Reaction Temp
-15 degree C, room temp
Solvent
Et2O, Et2O
Comment
1) +all, 2) temperature change
13 was added 2 minutes after the initiation of the reaction.
MS 4A was included in the solvent.
COMMENT
Keywords: glycosyl fluorides, glycosyl sulfides, hexasaccharide
There are multiple steps in this reaction.
ATTENTION: The reference is wrong.
REFERENCE
Reference Id
REF-0000-000196
Source
PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
REF-0000-000197
Source
ISBN 0-8247-9802-3
Reference Id
REF-0000-000226
Source
unknown

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