JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001729
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001729
Regist Date
 2012/06/21 17:45:17
REACTANT
MOLECULE ID
 JCGG-COM0002251 (Reaction Tree)
Reactant Type
 (in 1 mL of Et2O)
Mol
 0.057 mmol
MOLECULE ID
 JCGG-COM0002253 (Reaction Tree)
Reactant Type
 (in 1 mL of Et2O)
Mol
 0.074 mmol
MOLECULE ID
 JCGG-COM0000032
Reactant Type
 AgClO4
Mol
 0.06 mmol
MOLECULE ID
 JCGG-COM0000813
Reactant Type
 SnCl2
Mol
 0.06 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0002254 (Reaction Tree)
Yield
 62%
REACTION DETAIL
Reaction Time
 16 hours
Reaction Temp
 0 degree C
Solvent
 dry Et2O
Comment
 The reactants were mixed at -15 degree in Celsius before stirred at 0 degree.
MS 4A was included in the solvent.
COMMENT
Keywords: glycosyl fluorides, glycosyl sulfides, avermectin
REFERENCE
Reference Id
 REF-0000-000196
Source
 PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
 REF-0000-000197
Source
 ISBN 0-8247-9802-3
Reference Id
 REF-0000-000225
Source
 J. Am. Chem. Soc. 106:4189 (1984)
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)