Reaction:JCGG-RAC0001728

JCGG ID		JCGG-RAC0001728
Submitter		The Noguchi Institute
Reaction ID		R-0000-001728
Regist Date		2012/06/21 17:45:07
REACTANT
MOLECULE ID		JCGG-COM0002250 (Reaction Tree)
	Mol	0.11 mmol
MOLECULE ID		JCGG-COM0000810
	Reactant Type	DAST
	Mol	0.16 mmol
MOLECULE ID		JCGG-COM0000603
	Reactant Type	NBS
	Mol	0.14 mmol
PRODUCT
MOLECULE ID		JCGG-COM0002251 (Reaction Tree)
	Product Type	alpha
	Yield	85%(alpha/beta=5/1)
MOLECULE ID		JCGG-COM0002252 (Reaction Tree)
	Product Type	beta
	Yield	85%(alpha/beta=5/1)
REACTION DETAIL
Reaction Time		15 minutes
Reaction Temp		-15 degree C
Solvent		CH2Cl2
COMMENT
Keywords: glycosyl fluorides, glycosyl sulfides, avermectin
REFERENCE
Reference Id		REF-0000-000196
	Source	PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id		REF-0000-000197
	Source	ISBN 0-8247-9802-3
Reference Id		REF-0000-000225
	Source	J. Am. Chem. Soc. 106:4189 (1984)