JCGG ID |
JCGG-RAC0001716 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-001716 | |||||||
Regist Date |
2012/06/21 17:42:56 | |||||||
REACTANT | ||||||||
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Mol |
1 mmol | |||||||
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Mol |
1.2 mmol | |||||||
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Reactant Type |
BF3*OEt2 (0.1 M in Et2O/CH2Cl2=1/1) | |||||||
Volume |
1 mL | |||||||
PRODUCT | ||||||||
MOLECULE ID |
|
|
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Yield |
90% | |||||||
REACTION DETAIL | ||||||||
Reaction Time |
(5 to 10) + 15 minutes | |||||||
Reaction Temp |
0 degree C | |||||||
Solvent |
dry CH2Cl2 | |||||||
Comment |
38, 39, and MS 4A were mixed and stirred for 30 minutes at room temperature before the reaction. | |||||||
MS 4A was included in the solvent. | ||||||||
BF3*OEt2 was added dropwise within 5 to 10 minutes. | ||||||||
COMMENT | ||||||||
Keywords: glycosylation, O-glycosyl trichloroacetimidates | ||||||||
The reaction is the 1st part of the sequence. | ||||||||
REFERENCE | ||||||||
Reference Id |
REF-0000-000196 | |||||||
Source |
PREPARATIVE CARBOHYDRATE CHEMISTRY | |||||||
Reference Id |
REF-0000-000197 | |||||||
Source |
ISBN 0-8247-9802-3 | |||||||
Reference Id |
REF-0000-000216 | |||||||
Source |
Synthesis p. 694 (1988) |
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST) |