Reaction:JCGG-RAC0001715

JCGG ID		JCGG-RAC0001715
Submitter		The Noguchi Institute
Reaction ID		R-0000-001715
Regist Date		2012/06/21 17:42:54
REACTANT
MOLECULE ID		JCGG-COM0002226 (Reaction Tree)
	Mol	0.369 mmol
MOLECULE ID		JCGG-COM0001026
	Reactant Type	Pd/C (10%)
	Weight	390 mg
MOLECULE ID		JCGG-COM0000414
	Reactant Type	H2 (gas)
MOLECULE ID		JCGG-COM0000979
	Reactant Type	pyridine (solvent)
	Volume	5 mL
MOLECULE ID		JCGG-COM0000086
	Reactant Type	Ac2O (solvent)
	Volume	1 mL
PRODUCT
MOLECULE ID		JCGG-COM0002227 (Reaction Tree)
	Product Type	alpha
	Yield	91%(alpha/beta=32/1)
MOLECULE ID		JCGG-COM0002228 (Reaction Tree)
	Product Type	beta
	Yield	91%(alpha/beta=32/1)
REACTION DETAIL
Reaction Time		4 hours, 15 hours
Reaction Temp		NOT specified, room temp
Solvent		dioxane, pyridine/Ac2O = 5/1
Comment		1) 36+Pd/C, H2, 2) +all the rest
COMMENT
Keywords: glycosylation, O-glycosyl trichloroacetimidates
The reaction is the 2nd part of the sequence.
There are multiple steps in this reaction.
REFERENCE
Reference Id		REF-0000-000196
	Source	PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id		REF-0000-000197
	Source	ISBN 0-8247-9802-3
Reference Id		REF-0000-000215
	Source	Liebigs Ann. Chem. p. 543 (1993)