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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001714 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001714
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Regist Date |
2012/06/21 17:42:43 | ||||
| REACTANT | |||||
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Mol |
0.936 mmol | ||||
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Mol |
0.473 mmol | ||||
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Reactant Type |
TMSOTf (0.04 M in CH2Cl2) | ||||
Mol |
0.047 + 0.047 mmol | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
78% | ||||
| REACTION DETAIL | |||||
Reaction Time |
1 + 1 hours | ||||
Reaction Temp |
room temp | ||||
Solvent |
dry CH2Cl2 | ||||
Comment |
34, 35, and MS 4A were mixed and stirred for 10 minutes before the reaction. | ||||
| MS 4A was included in the solvent. | |||||
| TMSOTf was added twice. (0 hour, 1 hour) | |||||
| COMMENT | |||||
| Keywords: glycosylation, O-glycosyl trichloroacetimidates | |||||
| The reaction is the 1st part of the sequence. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000196 | ||||
Source |
PREPARATIVE CARBOHYDRATE CHEMISTRY | ||||
Reference Id |
REF-0000-000197 | ||||
Source |
ISBN 0-8247-9802-3 | ||||
Reference Id |
REF-0000-000215 | ||||
Source |
Liebigs Ann. Chem. p. 543 (1993) | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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