Reaction:JCGG-RAC0001711

JCGG ID

JCGG-RAC0001711

Submitter

The Noguchi Institute

Reaction ID

R-0000-001711

Regist Date

2012/06/21 17:42:07

REACTANT

MOLECULE ID

JCGG-COM0002214 (Reaction Tree)

Reactant Type

(in Et2O)

Mol

11.2 mmol

MOLECULE ID

JCGG-COM0002215 (Reaction Tree)

Skeleton

JCGG-STR025230

Mol

7.19 mmol

MOLECULE ID

JCGG-COM0000009

Reactant Type

TMSOTf (0.1 M)

Mol

0.1 mmol

PRODUCT

MOLECULE ID

JCGG-COM0002216 (Reaction Tree)

Yield

85%

REACTION DETAIL

Reaction Time

5 minutes

Reaction Temp

room temp

Solvent

dry Et2O

Comment

The addition of TMSOTf was performed before the addition of 25.

COMMENT

Keywords: glycosylation, O-glycosyl trichloroacetimidates

REFERENCE

Reference Id

REF-0000-000196

Source

PREPARATIVE CARBOHYDRATE CHEMISTRY

Reference Id

REF-0000-000197

Source

ISBN 0-8247-9802-3

Reference Id

REF-0000-000208

Source

Liebigs Ann. Chem. p. 449 (1994)