JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001710
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001710
Regist Date
 2012/06/21 17:41:56
REACTANT
MOLECULE ID
 JCGG-COM0002194 (Reaction Tree)
Skeleton
JCGG-STR032527
Mol
 16 mmol
MOLECULE ID
 JCGG-COM0002212 (Reaction Tree)
Skeleton
JCGG-STR019472
Mol
 12.5 mmol
MOLECULE ID
 JCGG-COM0000009
Reactant Type
 TMSOTf
Mol
 2.2 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0002213 (Reaction Tree)
Skeleton
JCGG-STR025422
Yield
 92%
REACTION DETAIL
Reaction Time
 20 minutes
Reaction Temp
 room temp
Solvent
 dry Et2O
Comment
 6, 23, and MS 4A were mixed and stirred for 10 minutes at room temperature before the reaction.
MS 4A was included in the solvent.
COMMENT
Keywords: glycosylation, O-glycosyl trichloroacetimidates
REFERENCE
Reference Id
 REF-0000-000196
Source
 PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
 REF-0000-000197
Source
 ISBN 0-8247-9802-3
Reference Id
 REF-0000-000211
Source
 Angew. Chem. 106:2289 (1994)
Reference Id
 REF-0000-000212
Source
 Angew. Chem. Int. Ed. Engl. 33:2177 (1994)
Reference Id
 REF-0000-000213
Source
 Thomas G. Mayer, Dissertation, Universitat Konstanz, 1995, submitted
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)