Reaction:JCGG-RAC0001707

JCGG ID

JCGG-RAC0001707

Submitter

The Noguchi Institute

Reaction ID

R-0000-001707

Regist Date

2012/06/21 17:40:57

REACTANT

MOLECULE ID

JCGG-COM0002203 (Reaction Tree)

Skeleton

JCGG-STR031555

Mol

4.42 mmol

MOLECULE ID

JCGG-COM0002204 (Reaction Tree)

Mol

2.21 mmol

MOLECULE ID

JCGG-COM0000009

Reactant Type

TMSOTf (0.033 M in Et2O)

Mol

50 micro mole

PRODUCT

MOLECULE ID

JCGG-COM0002205 (Reaction Tree)

Yield

75%

REACTION DETAIL

Reaction Time

5 hours

Reaction Temp

-20 degree C

Solvent

dry Et2O

Comment

TMSOTf was added dropwise.

COMMENT

Keywords: glycosylation, O-glycosyl trichloroacetimidates

REFERENCE

Reference Id

REF-0000-000196

Source

PREPARATIVE CARBOHYDRATE CHEMISTRY

Reference Id

REF-0000-000197

Source

ISBN 0-8247-9802-3

Reference Id

REF-0000-000210

Source

Liebigs Ann. Chem. p. 607 (1991)