JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001697
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001697
Regist Date
 2012/06/21 17:38:43
REACTANT
MOLECULE ID
 JCGG-COM0002183 (Reaction Tree)
Mol
 0.305 mmol
MOLECULE ID
 JCGG-COM0002184
Reactant Type
 5,5-dimethyl-cyclohexane-1,3-dion
Mol
 7.1 mmol
MOLECULE ID
 JCGG-COM0000646
Reactant Type
 [(C6H5)3P]4Pd
Mol
 0.043 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0002185 (Reaction Tree)
Yield
 91%
REACTION DETAIL
Reaction Time
 2 hours
Reaction Temp
 NOT specified
Solvent
 oxygen-free THF
Comment
 The reaction was conducted in dark condition.
COMMENT
Keywords: O-glycopeptide, N-glycopeptide, synthesis, selectively deprotected building blocks, allyloxycarbonyl group
REFERENCE
Reference Id
 REF-0000-000196
Source
 PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
 REF-0000-000197
Source
 ISBN 0-8247-9802-3
Reference Id
 REF-0000-000201
Source
 Angew. Chem. Int. Ed. Engl. 27:1697 (1988)
Reference Id
 REF-0000-000202
Source
 Angew. Chem. Int. Ed. Engl. 23:436 (1984)
Reference Id
 REF-0000-000203
Source
 Bioorg. Med. Chem. 2:1189 (1994)
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)