JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001695
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001695
Regist Date
 2012/06/21 17:38:19
REACTANT
MOLECULE ID
 JCGG-COM0002178 (Reaction Tree)
Reactant Type
 1-O-tert-butyl aspartate
Mol
 15.9 mmol
MOLECULE ID
 JCGG-COM0002179
Reactant Type
 KHCO3
Mol
 32 mmol
MOLECULE ID
 JCGG-COM0002180
Reactant Type
 allyl chloroformate
Mol
 16 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0002181 (Reaction Tree)
Yield
 89%
REACTION DETAIL
Reaction Time
 1 hour
Reaction Temp
 0 degree C
Solvent
 H2O
COMMENT
Keywords: O-glycopeptide, N-glycopeptide, synthesis, selectively deprotected building blocks, allyloxycarbonyl group
REFERENCE
Reference Id
 REF-0000-000196
Source
 PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
 REF-0000-000197
Source
 ISBN 0-8247-9802-3
Reference Id
 REF-0000-000201
Source
 Angew. Chem. Int. Ed. Engl. 27:1697 (1988)
Reference Id
 REF-0000-000202
Source
 Angew. Chem. Int. Ed. Engl. 23:436 (1984)
Reference Id
 REF-0000-000203
Source
 Bioorg. Med. Chem. 2:1189 (1994)
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)