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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001693 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001693
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Regist Date |
2012/06/21 17:38:03 | ||||
| REACTANT | |||||
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Mol |
1.88 mol | ||||
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Reactant Type |
(in 5 mL of CH2Cl2) | ||||
Mol |
6 mmol | ||||
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Reactant Type |
Et4N+*Br- | ||||
Mol |
19 mmol | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
74% | ||||
| REACTION DETAIL | |||||
Reaction Time |
4 days | ||||
Reaction Temp |
NOT specified | ||||
Solvent |
DMF/CH2Cl2 = 2/1 | ||||
Comment |
Et4N+*Br-, 30, and MS 4A were mixed and stirred for 30 minutes before the reaction. | ||||
| MS 4A was included in the solvent. | |||||
| 31 was added dropwise. | |||||
| COMMENT | |||||
| Keywords: O-glycopeptide, N-glycopeptide, synthesis, selectively deprotected building blocks, allyloxycarbonyl group | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000196 | ||||
Source |
PREPARATIVE CARBOHYDRATE CHEMISTRY | ||||
Reference Id |
REF-0000-000197 | ||||
Source |
ISBN 0-8247-9802-3 | ||||
Reference Id |
REF-0000-000201 | ||||
Source |
Angew. Chem. Int. Ed. Engl. 27:1697 (1988) | ||||
Reference Id |
REF-0000-000202 | ||||
Source |
Angew. Chem. Int. Ed. Engl. 23:436 (1984) | ||||
Reference Id |
REF-0000-000203 | ||||
Source |
Bioorg. Med. Chem. 2:1189 (1994) | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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