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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001676 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-001676
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Regist Date |
2012/06/21 17:36:09 | |||||||
| REACTANT | ||||||||
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Mol |
21.2 mmol | |||||||
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Mol |
20 mmol | |||||||
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Reactant Type |
AgOTf (in dry CH2Cl2) | |||||||
Mol |
30 mmol | |||||||
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Reactant Type |
(Me2N)2CO | |||||||
Mol |
31.4 mmol | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
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Yield |
87% | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
18 hours | |||||||
Reaction Temp |
room temp | |||||||
Solvent |
dry CH2Cl2 | |||||||
Comment |
The reactants were mixed at -40 degree in Celsius before stirred at room temperature. | |||||||
| The reaction was conducted in dark condition. | ||||||||
| AgOTf was added dropwise. | ||||||||
| COMMENT | ||||||||
| Keywords: O-glycopeptide, N-glycopeptide, synthesis, selectively deprotected building blocks, fluorenylmethoxycarbonyl group, Fmoc, benzyl esters | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000196 | |||||||
Source |
PREPARATIVE CARBOHYDRATE CHEMISTRY | |||||||
Reference Id |
REF-0000-000197 | |||||||
Source |
ISBN 0-8247-9802-3 | |||||||
Reference Id |
REF-0000-000198 | |||||||
Source |
Angew. Chem. Int. Ed. Engl. 22:62 (1983) | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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