JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001669
Submitter
The Noguchi Institute
Reaction ID
R-0000-001669
Regist Date
2012/06/21 17:34:40
REACTANT
MOLECULE ID
JCGG-COM0002131 (Reaction Tree)
Reactant Type
thioglycoside
Mol
4.1 mmol
MOLECULE ID
JCGG-COM0002132 (Reaction Tree)
Skeleton
JCGG-STR031569
Reactant Type
alcohol
Mol
4.0 mmol
MOLECULE ID
JCGG-COM0000741
Reactant Type
MeOTf
Mol
20 mmol
PRODUCT
MOLECULE ID
JCGG-COM0002133 (Reaction Tree)
Yield
83%
REACTION DETAIL
Reaction Time
8 hours
Reaction Temp
room temp
Solvent
CH2Cl2
Comment
Thioglycoside, alcohol, and MS 4A were mixed and stirred for 30 minutes at room temperature before the reaction.
MS 4A was included in the solvent.
COMMENT
Keywords: plant cell wall, glycan, phytoalexin elicitor
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000195
Source
P. Fugedi, W. Birberg, P. J. Garegg, and A. Pilotti, Carbohydr. Res., 164, 297 (1987)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)