Reaction:JCGG-RAC0001657

JCGG ID

JCGG-RAC0001657

Submitter

The Noguchi Institute

Reaction ID

R-0000-001657

Regist Date

2012/06/21 17:33:07

REACTANT

MOLECULE ID

JCGG-COM0000601 (Reaction Tree)

Skeleton

JCGG-STR031555

Reactant Type

acetate

Mol

9 mmol

MOLECULE ID

JCGG-COM0002117 (Reaction Tree)

Skeleton

JCGG-STR028522

Reactant Type

alcohol

Mol

10 mmol

MOLECULE ID

JCGG-COM0000009

Reactant Type

TMSOTf

Volume

0.2 mL

PRODUCT

MOLECULE ID

JCGG-COM0002118 (Reaction Tree)

Yield

71%

REACTION DETAIL

Reaction Time

6 hours

Reaction Temp

20 degree C

Solvent

ClCH2CH2Cl

Comment

Acetate, alcohol, and MS 4A were mixed and stirred for 1 hour at 20 degree in Celsius before the reaction.

MS 4A was included in the solvent.

COMMENT

Keywords: synthesis of glycopeptide, O-glycan

REFERENCE

Reference Id

REF-0000-000073

Source

第4版実験化学講座 (26), 丸善

Reference Id

REF-0000-000074

Source

ISBN 4-621-03702-1

Reference Id

REF-0000-000194

Source

H. Paulsen and M. Paal, Carbohydr. Res., 135, 53 (1984) ; H. Paulsen and M. Paal, ibid., 135, 71 (1984)