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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001623 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-001623
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Regist Date |
2012/06/21 17:27:23 | |||||||
| REACTANT | ||||||||
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Reactant Type |
fluoride | |||||||
Mol |
0.15 mmol | |||||||
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Reactant Type |
alcohol | |||||||
Weight |
660 mg | |||||||
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Reactant Type |
AgClO4 | |||||||
Weight |
62 mg | |||||||
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Reactant Type |
SnCl2 | |||||||
Weight |
57 mg | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
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Yield |
80% | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
10 minutes + 12 hours | |||||||
Reaction Temp |
0 degree C to room temp | |||||||
Solvent |
CH2Cl2/2,6-lutidine = 4mL/17microL | |||||||
Comment |
MS 4A was included in the solvent. | |||||||
| The reactants were mixed at 0 degree in Celsius, and stirred for 10 minutes before stirred at room temperature. | ||||||||
| The alcohol was added 10 minutes after the initiation of the reaction. | ||||||||
| COMMENT | ||||||||
| Keywords: synthesis of glycosphingolipid, globotriosylceramide, Gb3 | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000073 | |||||||
Source |
第4版 実験化学講座 (26), 丸善 | |||||||
Reference Id |
REF-0000-000074 | |||||||
Source |
ISBN 4-621-03702-1 | |||||||
Reference Id |
REF-0000-000191 | |||||||
Source |
K. C. Nicolaou, T. J. Caulfield, and H. Kataoka, Carbohydr. Res., 202, 177 (1990) | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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