JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001616
Submitter
The Noguchi Institute
Reaction ID
R-0000-001616
Regist Date
2012/06/21 17:26:26
REACTANT
MOLECULE ID
JCGG-COM0002064 (Reaction Tree)
MOLECULE ID
JCGG-COM0001065
Reactant Type
t-BuCOCl
MOLECULE ID
JCGG-COM0000500
Reactant Type
DMAP
PRODUCT
MOLECULE ID
JCGG-COM0002065 (Reaction Tree)
Yield
78%(at least)
REACTION DETAIL
Reaction Time
NOT specified
Reaction Temp
75 degree C
Solvent
pyridine
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: synthesis of glycosphingolipid, globotriosylceramide, Gb3
The reaction is the 2nd part of the sequence.
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000191
Source
K. C. Nicolaou, T. J. Caulfield, and H. Kataoka, Carbohydr. Res., 202, 177 (1990)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)