Reaction:JCGG-RAC0001608

JCGG ID		JCGG-RAC0001608
Submitter		The Noguchi Institute
Reaction ID		R-0000-001608
Regist Date		2012/06/21 17:25:34
REACTANT
MOLECULE ID		JCGG-COM0002052 (Reaction Tree)
	Mol	0.632 mmol
MOLECULE ID		JCGG-COM0000530
	Reactant Type	NaOMe (0.5 M methanolic solution)
	Volume	0.27 mL
MOLECULE ID		JCGG-COM0001871
	Reactant Type	FeCl3 (in acetone)
	Mol	0.11 mmol
PRODUCT
MOLECULE ID		JCGG-COM0002053 (Reaction Tree)
	Yield	40%
MOLECULE ID		JCGG-COM0002054 (Reaction Tree)
	Product Type	isomer
	Yield	18%
REACTION DETAIL
Reaction Time		overnight, 30 minutes
Reaction Temp		room temp, reflux
Solvent		MeOH, acetone
Comment		1) 3+NaOMe, 2) +FeCl3
COMMENT
Keywords: biological activity, carbohydrates, conformation analysis, lectins, synthesis design
There are multiple phases in this reaction.
REFERENCE
Reference Id		REF-0000-000189
	Issn	Print
	Doi	10.1002/chem.200400831
	PubMed ID	15770712
	Journal Name	Chemistry (Weinheim an der Bergstrasse, Germany). (2005) 11 (10): 3032-8.
	Article Title	Synthesis and evaluation of 5-thio-L-fucose-containing oligosaccharide.
	Author	Masayuki, Izumi; Osamu, Tsuruta; Yasuhiro, Kajihara; Shin, Yazawa; Hideya, Yuasa; Hironobu, Hashimoto
	Affiliation	Department of Life Science, Graduate school of Bioscience and Biotechnology, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama 226-8501, Japan.masayuki.izumi@aist.go.jp
Reference Id		REF-0000-000190
	Source	Chem. Eur. J. 2005, 11, 3032-3038
	Doi	10.1002/chem.200400831