JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001587
Submitter
The Noguchi Institute
Reaction ID
R-0000-001587
Regist Date
2012/06/21 17:23:36
REACTANT
MOLECULE ID
JCGG-COM0002021 (Reaction Tree)
Reactant Type
donor
Mol
0.045 mmol
MOLECULE ID
JCGG-COM0000068 (Reaction Tree)
Skeleton
JCGG-STR032525
Reactant Type
acceptor
Mol
0.030 mmol
MOLECULE ID
JCGG-COM0000229
Reactant Type
promoter
Mol
0.045 mmol
PRODUCT
MOLECULE ID
JCGG-COM0002035 (Reaction Tree)
Skeleton
JCGG-STR002224
Product Type
beta
Yield
83%
REACTION DETAIL
Reaction Time
144 hours
Reaction Temp
room temp
Solvent
ClCH2CH2Cl
Comment
The donor, the acceptor, and MS 4A were mixed and stirred for 1 hour before the reaction.
COMMENT
Keywords: carbohydrates, glycosides, glycosylation, oligosaccharides, synthetic methods
REFERENCE
Reference Id
REF-0000-000187
Issn
Electronic
Doi
10.1002/anie.201007212
PubMed ID
21433229
Journal Name
Angewandte Chemie (International ed. in English). (2011) 50 (18): 4197-201.
Article Title
S-Benzimidazolyl glycosides as a platform for oligosaccharide synthesis by an active-latent strategy.
Author
Scott J, Hasty; Matthew A, Kleine; Alexei V, Demchenko
Affiliation
Department of Chemistry and Biochemistry, University of Missouri-St.?Louis, One University Boulevard, St.?Louis, MO 63121, USA.
Reference Id
REF-0000-000188
Source
Angew. Chem. Int. Ed. 2011, 50, 4197-4201
Doi
10.1002/anie.201007212

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)