|
Glycan Syntheses |
JCGG ID |
JCGG-RAC0001575 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-001575
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Regist Date |
2012/06/21 17:22:39 | |||||||
| REACTANT | ||||||||
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Reactant Type |
glucopyranoside | |||||||
Mol |
2.05 mmol | |||||||
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|
|||||||
Reactant Type |
2-mercaptobenzimidazole | |||||||
Mol |
5.11 mmol | |||||||
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|||||||
Reactant Type |
HgBr2 | |||||||
Mol |
0.205 mmol | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
|
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Yield |
86% | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
6 hours | |||||||
Reaction Temp |
reflux | |||||||
Solvent |
MeCN | |||||||
Comment |
The glucopyranoside and MS 3A were mixed and stirred for 1 hour at room temperature before the reaction. | |||||||
| COMMENT | ||||||||
| Keywords: carbohydrates, glycosides, glycosylation, oligosaccharides, synthetic methods | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000187 | |||||||
Issn |
Electronic | |||||||
Doi |
10.1002/anie.201007212 | |||||||
PubMed ID |
21433229 | |||||||
Journal Name |
Angewandte Chemie (International ed. in English). (2011) 50 (18): 4197-201. | |||||||
Article Title |
S-Benzimidazolyl glycosides as a platform for oligosaccharide synthesis by an active-latent strategy. | |||||||
Author |
Scott J, Hasty; Matthew A, Kleine; Alexei V, Demchenko | |||||||
Affiliation |
Department of Chemistry and Biochemistry, University of Missouri-St.？Louis, One University Boulevard, St.？Louis, MO 63121, USA. | |||||||
Reference Id |
REF-0000-000188 | |||||||
Source |
Angew. Chem. Int. Ed. 2011, 50, 4197-4201 | |||||||
Doi |
10.1002/anie.201007212 | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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