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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001564 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001564
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Regist Date |
2012/06/21 17:21:39 | ||||
| REACTANT | |||||
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Mol |
1.77 mmol | ||||
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Reactant Type |
TMSCl | ||||
Mol |
26.6 mmol | ||||
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Reactant Type |
anisoyl chloride | ||||
Mol |
3.55 mmol | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
89% | ||||
| REACTION DETAIL | |||||
Reaction Time |
1 hour, 1 hour | ||||
Reaction Temp |
room temp, room temp | ||||
Solvent |
pyridine, pyridine | ||||
Comment |
1) B+TMSCl, 2) +anisoyl chloride | ||||
| Both TMSCl and anisoyl chloride were added dropwise. | |||||
| COMMENT | |||||
| Keywords: carbohydrates, glycosides, glycosylation, oligosaccharides, synthetic methods | |||||
| There are multiple phases in this reaction. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000187 | ||||
Issn |
Electronic | ||||
Doi |
10.1002/anie.201007212 | ||||
PubMed ID |
21433229 | ||||
Journal Name |
Angewandte Chemie (International ed. in English). (2011) 50 (18): 4197-201. | ||||
Article Title |
S-Benzimidazolyl glycosides as a platform for oligosaccharide synthesis by an active-latent strategy. | ||||
Author |
Scott J, Hasty; Matthew A, Kleine; Alexei V, Demchenko | ||||
Affiliation |
Department of Chemistry and Biochemistry, University of Missouri-St.？Louis, One University Boulevard, St.？Louis, MO 63121, USA. | ||||
Reference Id |
REF-0000-000188 | ||||
Source |
Angew. Chem. Int. Ed. 2011, 50, 4197-4201 | ||||
Doi |
10.1002/anie.201007212 | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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