JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001552
Submitter
The Noguchi Institute
Reaction ID
R-0000-001552
Regist Date
2012/06/21 17:20:14
REACTANT
MOLECULE ID
JCGG-COM0001992 (Reaction Tree)
Skeleton
JCGG-STR025280
Reactant Type
disaccharide
MOLECULE ID
JCGG-COM0000830
Reactant Type
Bu2SnO
MOLECULE ID
JCGG-COM0000419
Reactant Type
AllylBr
PRODUCT
MOLECULE ID
JCGG-COM0001993 (Reaction Tree)
Skeleton
JCGG-STR025280
Yield
70%
REACTION DETAIL
Reaction Time
NOT specified, NOT specified
Reaction Temp
reflux, NOT specified
Solvent
PhH, Bu4NBr
Comment
1) disaccharide+Bu2SnO, 2) +AllylBr
Very few were described regarding this reaction.
COMMENT
Keywords: protection of sugar hydroxy groups, ether group protection
There are multiple steps in this reaction.
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000181
Source
J. Alais, A. Maranduba, and A. Veyrieres, Tetrahedron Lett., 24, 2383 (1983)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)