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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001538 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001538
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Regist Date |
2012/06/21 17:18:31 | ||||
| REACTANT | |||||
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Reactant Type |
POCl3 | ||||
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Reactant Type |
Et3N | ||||
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Reactant Type |
Bu3SnH | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
97% | ||||
| REACTION DETAIL | |||||
Reaction Time |
NOT specified, NOT specified | ||||
Reaction Temp |
NOT specified, NOT specified | ||||
Solvent |
CH2Cl2, NOT specified | ||||
Comment |
1) +all except Bu3SnH, 2) +Bu3SnH | ||||
| Very few were described regarding this reaction. | |||||
| COMMENT | |||||
| The synthesis of 2-deoxy-glycoside, stereoselectivity control using C-2 substitution group | |||||
| The reaction is the 2nd part of the sequence. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000073 | ||||
Source |
第4版 実験化学講座 (26), 丸善 | ||||
Reference Id |
REF-0000-000074 | ||||
Source |
ISBN 4-621-03702-1 | ||||
Reference Id |
REF-0000-000170 | ||||
Source |
M. Trumtel, P. Tavecchiea, A. Veyrieres, and P. Sinay, Carbohydr. Res., 191, 29 (1989) | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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