JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001537
Submitter
The Noguchi Institute
Reaction ID
R-0000-001537
Regist Date
2012/06/21 17:18:23
REACTANT
MOLECULE ID
JCGG-COM0001958 (Reaction Tree)
Skeleton
JCGG-STR025230
MOLECULE ID
JCGG-COM0001959 (Reaction Tree)
Skeleton
JCGG-STR031555
MOLECULE ID
JCGG-COM0000009
Reactant Type
TMSOTf
PRODUCT
MOLECULE ID
JCGG-COM0001960 (Reaction Tree)
Yield
94%
REACTION DETAIL
Reaction Time
NOT specified
Reaction Temp
NOT specified
Solvent
CH2Cl2
Comment
Very few were described regarding this reaction.
COMMENT
The synthesis of 2-deoxy-glycoside, stereoselectivity control using C-2 substitution group
The reaction is the 1st part of the sequence.
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000170
Source
M. Trumtel, P. Tavecchiea, A. Veyrieres, and P. Sinay, Carbohydr. Res., 191, 29 (1989)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)