JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001529
Submitter
The Noguchi Institute
Reaction ID
R-0000-001529
Regist Date
2012/06/21 17:17:22
REACTANT
MOLECULE ID
JCGG-COM0001942 (Reaction Tree)
MOLECULE ID
JCGG-COM0001943 (Reaction Tree)
Skeleton
JCGG-STR032525
MOLECULE ID
JCGG-COM0000813
Reactant Type
SnCl2
PRODUCT
MOLECULE ID
JCGG-COM0001944 (Reaction Tree)
Product Type
alpha
Yield
92%(alpha/beta=10/1)
MOLECULE ID
JCGG-COM0001945 (Reaction Tree)
Product Type
beta
Yield
92%(alpha/beta=10/1)
REACTION DETAIL
Reaction Time
NOT specified
Reaction Temp
NOT specified
Solvent
CH2Cl2
Comment
Very few were described regarding this reaction.
COMMENT
The synthesis of 2-deoxy-glycoside, stereoselectivity control using C-2 substitution group
The reaction is the 3rd part of the sequence.
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000167
Source
K. C. Nicolaou, T. Ladduwahetty, J. L. Randall, and A. Chucholowski, J. Am. Chem. Soc., 108, 2466 (1986)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)