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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001528 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-001528
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Regist Date |
2012/06/21 17:17:20 | |||||||
| REACTANT | ||||||||
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Reactant Type |
SnCl2 | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
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Product Type |
alpha | |||||||
Yield |
92%(alpha/beta=1/16) | |||||||
MOLECULE ID |
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Product Type |
beta | |||||||
Yield |
92%(alpha/beta=1/16) | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
NOT specified | |||||||
Reaction Temp |
NOT specified | |||||||
Solvent |
Et2O | |||||||
Comment |
Very few were described regarding this reaction. | |||||||
| COMMENT | ||||||||
| The synthesis of 2-deoxy-glycoside, stereoselectivity control using C-2 substitution group | ||||||||
| The reaction is the 2nd part of the sequence. | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000073 | |||||||
Source |
第4版 実験化学講座 (26), 丸善 | |||||||
Reference Id |
REF-0000-000074 | |||||||
Source |
ISBN 4-621-03702-1 | |||||||
Reference Id |
REF-0000-000167 | |||||||
Source |
K. C. Nicolaou, T. Ladduwahetty, J. L. Randall, and A. Chucholowski, J. Am. Chem. Soc., 108, 2466 (1986) | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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