Reaction:JCGG-RAC0001525

JCGG ID		JCGG-RAC0001525
Submitter		The Noguchi Institute
Reaction ID		R-0000-001525
Regist Date		2012/06/21 17:16:56
REACTANT
MOLECULE ID		JCGG-COM0001937 (Reaction Tree)
MOLECULE ID		JCGG-COM0000647
	Reactant Type	Na2CO3
MOLECULE ID		JCGG-COM0000414
	Reactant Type	H2
MOLECULE ID		JCGG-COM0001026
	Reactant Type	Pd-C
MOLECULE ID		JCGG-COM0000086
	Reactant Type	Ac2O
PRODUCT
MOLECULE ID		JCGG-COM0001938 (Reaction Tree)
	Yield	59%
REACTION DETAIL
Reaction Time		NOT specified, NOT specified, NOT specified
Reaction Temp		NOT specified, NOT specified, NOT specified
Solvent		MeOH, Et3N/AcOEt, pyridine
Comment		1) bromide+Na2CO3, 2) +H2, Pd-C, 3) +Ac2O
		Very few were described regarding this reaction.
COMMENT
Keywords: The synthesis of 2-deoxy-glycoside, stereoselectivity control using C-2 substitution group
There are multiple steps in this reaction.
The reaction is the 3rd part of the sequence.
REFERENCE
Reference Id		REF-0000-000073
	Source	第4版実験化学講座 (26), 丸善
Reference Id		REF-0000-000074
	Source	ISBN 4-621-03702-1
Reference Id		REF-0000-000165
	Source	J. Thiem and M. Gerken, J. Carbohydr. Chem., 1, 229 (1982)