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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001524 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001524
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Regist Date |
2012/06/21 17:16:51 | ||||
| REACTANT | |||||
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Reactant Type |
AgOTf | ||||
| PRODUCT | |||||
MOLECULE ID |
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Product Type |
alpha | ||||
Yield |
92%(alpha/beta=1/6.5) | ||||
MOLECULE ID |
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Product Type |
beta | ||||
Yield |
92%(alpha/beta=1/6.5) | ||||
| REACTION DETAIL | |||||
Reaction Time |
NOT specified | ||||
Reaction Temp |
NOT specified | ||||
Solvent |
MeNO2, PhCH3 | ||||
Comment |
Very few were described regarding this reaction. | ||||
| MS 4A was included in the solvent. | |||||
| COMMENT | |||||
| Keywords: The synthesis of 2-deoxy-glycoside, stereoselectivity control using C-2 substitution group | |||||
| The reaction is the 2nd part of the sequence. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000073 | ||||
Source |
第4版 実験化学講座 (26), 丸善 | ||||
Reference Id |
REF-0000-000074 | ||||
Source |
ISBN 4-621-03702-1 | ||||
Reference Id |
REF-0000-000165 | ||||
Source |
J. Thiem and M. Gerken, J. Carbohydr. Chem., 1, 229 (1982) | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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