JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001522
Submitter
The Noguchi Institute
Reaction ID
R-0000-001522
Regist Date
2012/06/21 17:16:34
REACTANT
MOLECULE ID
JCGG-COM0001242 (Reaction Tree)
MOLECULE ID
JCGG-COM0001929 (Reaction Tree)
MOLECULE ID
JCGG-COM0001930
Reactant Type
PhSS(+)Ph2*SbCl6(-)
PRODUCT
MOLECULE ID
JCGG-COM0001931 (Reaction Tree)
Product Type
beta
Yield
75%(beta/alpha=11.5/1)
MOLECULE ID
JCGG-COM0001932 (Reaction Tree)
Product Type
alpha
Yield
75%(beta/alpha=11.5/1)
REACTION DETAIL
Reaction Time
NOT specified
Reaction Temp
-60 degree C
Solvent
CH2Cl2
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: The synthesis of 2-deoxy-glycoside, glycal donor
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000164
Source
S. Ramesh, N. Kaila, G. Grewal, and R. W. Franck, J. Org. Chem., 55, 5 (1990)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)