|
Glycan Syntheses |
JCGG ID |
JCGG-RAC0001521 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-001521
|
|||||||
Regist Date |
2012/06/21 17:16:21 | |||||||
| REACTANT | ||||||||
|
|
|
|||||||
|
|
|
|
||||||
|
|
|
|||||||
Reactant Type |
TMSOTf | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
|
|
||||||
Product Type |
beta | |||||||
Yield |
81%(beta/alpha=4/1) | |||||||
MOLECULE ID |
|
|
||||||
Product Type |
alpha | |||||||
Yield |
81%(beta/alpha=4/1) | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
20 minutes | |||||||
Reaction Temp |
-15 degree C | |||||||
Solvent |
PhCH3 | |||||||
Comment |
Very few were described regarding this reaction. | |||||||
| MS 4A was included in the solvent. | ||||||||
| COMMENT | ||||||||
| Keywords: The synthesis of 2-deoxy-glycoside, glycal donor | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000073 | |||||||
Source |
第4版 実験化学講座 (26), 丸善 | |||||||
Reference Id |
REF-0000-000074 | |||||||
Source |
ISBN 4-621-03702-1 | |||||||
Reference Id |
REF-0000-000163 | |||||||
Source |
Y. Ito and T. Ogawa, Tetrahedron Lett., 28, 2723 (1987) | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
|
