Reaction:JCGG-RAC0001516

JCGG ID

JCGG-RAC0001516

Submitter

The Noguchi Institute

Reaction ID

R-0000-001516

Regist Date

2012/06/21 17:15:42

REACTANT

MOLECULE ID

JCGG-COM0001917 (Reaction Tree)

Reactant Type

glycal

Mol

0.44 mmol

MOLECULE ID

JCGG-COM0001706 (Reaction Tree)

Skeleton

JCGG-STR031569

Reactant Type

alcohol

Mol

0.66 mmol

MOLECULE ID

JCGG-COM0000603

Reactant Type

NBS

Mol

0.53 mmol

PRODUCT

MOLECULE ID

JCGG-COM0001918 (Reaction Tree)

Yield

88%

REACTION DETAIL

Reaction Time

0.5 hour, 1 hour

Reaction Temp

5 degree C, room temp

Solvent

MeCN/Et2O = 1/1, MeCN/Et2O = 1/1

Comment

1) +all, 2) temperature change

COMMENT

Keywords: The synthesis of 2-deoxy-glycoside, glycal donor

There are multiple steps in this reaction.

The reaction is the 1st part of the sequence.

REFERENCE

Reference Id

REF-0000-000073

Source

第4版実験化学講座 (26), 丸善

Reference Id

REF-0000-000074

Source

ISBN 4-621-03702-1

Reference Id

REF-0000-000159

Source

K. Tatsuta, K. Fujimoto, M. Kinoshita, and S. Umezawa, Carbohydr. Res., 54, 85 (1977)