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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001515 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001515
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Regist Date |
2012/06/21 17:15:35 | ||||
| REACTANT | |||||
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Reactant Type |
bromide | ||||
Weight |
110g | ||||
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Reactant Type |
Zn | ||||
Weight |
100g + 200g | ||||
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Reactant Type |
H2PtCl6 (3% in H2O) | ||||
Volume |
1 mL + few drops | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
66%(approximately, 48g) | ||||
| REACTION DETAIL | |||||
Reaction Time |
NOT specified, 2 + 3 hours | ||||
Reaction Temp |
NOT specified, NOT specified | ||||
Solvent |
AcOH(50%), AcOH(50%) | ||||
Comment |
1) bromide+Zn(100g), H2PtCl6 solution(1mL), 2) +all the rest | ||||
| The second addition of both Zn (200g) and H2PtCl6 solution (few drops) was performed over 2 hours. (second phase) | |||||
| COMMENT | |||||
| Keywords: The synthesis of 2-deoxy-glycoside, glycal donor | |||||
| There are multiple steps in this reaction. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000073 | ||||
Source |
第4版 実験化学講座 (26), 丸善 | ||||
Reference Id |
REF-0000-000074 | ||||
Source |
ISBN 4-621-03702-1 | ||||
Reference Id |
REF-0000-000158 | ||||
Source |
F. Shafizadeh, ibid., 2, 409 (1963) | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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