Reaction:JCGG-RAC0001511

JCGG ID		JCGG-RAC0001511
Submitter		The Noguchi Institute
Reaction ID		R-0000-001511
Regist Date		2012/06/21 17:14:46
REACTANT
MOLECULE ID		JCGG-COM0001898 (Reaction Tree)
	Reactant Type	donor
	Mol	0.29 mmol
MOLECULE ID		JCGG-COM0001899
	Reactant Type	acceptor (in 25 mL of CH2Cl2)
	Mol	0.23 mmol
MOLECULE ID		JCGG-COM0000009
	Reactant Type	TMSOTf
	Mol	0.62 mmol
PRODUCT
MOLECULE ID		JCGG-COM0001900 (Reaction Tree)
	Yield	99.5%
REACTION DETAIL
Reaction Time		NOT specified, 1 hour, 5 hours
Reaction Temp		-40 degree C, 0 degree C, -15 degree C
Solvent		CH2Cl2/Et2O = 12mL/10mL, CH2Cl2/Et2O = 12mL/10mL, CH2Cl2/Et2O = 12mL/10mL
Comment		1) donor+MS 4A, 2) +TMSOTf, 3) +acceptor
		MS 4A was included in the solvent.
COMMENT
The synthesis of 2-deoxy-glycoside, 2-deoxy-sugar donor
REFERENCE
Reference Id		REF-0000-000073
	Source	第4版実験化学講座 (26), 丸善
Reference Id		REF-0000-000074
	Source	ISBN 4-621-03702-1
Reference Id		REF-0000-000154
	Source	Y. Kimura, M. Suzuki, T. Matsumoto, R. Abe, and S. Terashima, Bull. Chem. Soc. Jpn., 59, 423 (1986)