JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001495
Submitter
The Noguchi Institute
Reaction ID
R-0000-001495
Regist Date
2012/06/21 17:12:20
REACTANT
MOLECULE ID
JCGG-COM0001857 (Reaction Tree)
MOLECULE ID
JCGG-COM0001858
MOLECULE ID
JCGG-COM0001699
Reactant Type
Ag2CO3
MOLECULE ID
JCGG-COM0000032
Reactant Type
AgClO4
PRODUCT
MOLECULE ID
JCGG-COM0001859 (Reaction Tree)
Product Type
alpha
Yield
83%(alpha/beta=20/1)
MOLECULE ID
JCGG-COM0001860 (Reaction Tree)
Product Type
beta
Yield
83%(alpha/beta=20/1)
REACTION DETAIL
Reaction Time
NOT specified
Reaction Temp
NOT specified
Solvent
CH2Cl2, PhCH3
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: The synthesis of 2-aminoglycoside, alpha-2-aminoglycoside
The reaction is the 1st part of the sequence.
ATTENTION: There is an error in the chemical structure. (HO(CH2)7CO2CH3 should be HO(CH2)8CO2CH3)
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000142
Source
H. Paulsen and M. Paal, Carbohydr. Res., 135, 71 (1984)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)