JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001491
Submitter
The Noguchi Institute
Reaction ID
R-0000-001491
Regist Date
2012/06/21 17:11:32
REACTANT
MOLECULE ID
JCGG-COM0001845 (Reaction Tree)
MOLECULE ID
JCGG-COM0001846 (Reaction Tree)
Skeleton
JCGG-STR031569
PRODUCT
MOLECULE ID
JCGG-COM0001847 (Reaction Tree)
Yield
80%
REACTION DETAIL
Reaction Time
30 minutes
Reaction Temp
140 degree C
Solvent
NOT specified
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: The synthesis of 1,2-trans-glycoside, alpha-mannopyranoside
This reaction employed a unique method called thermal glycosidation. (generally poor selectivity except alpha-mannoglycosidation)
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000138
Source
M. Nishizawa, Y. Kan, W. Shimomoto, and H. Yamada, Tetrahedron Lett., 31, 2431 (1990)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)