JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001483
Submitter
The Noguchi Institute
Reaction ID
R-0000-001483
Regist Date
2012/06/21 17:10:11
REACTANT
MOLECULE ID
JCGG-COM0001681 (Reaction Tree)
MOLECULE ID
JCGG-COM0001824 (Reaction Tree)
Skeleton
JCGG-STR032525
MOLECULE ID
JCGG-COM0001825
Reactant Type
SiF4
PRODUCT
MOLECULE ID
JCGG-COM0000069 (Reaction Tree)
Skeleton
JCGG-STR005065
Product Type
alpha
Yield
90%(alpha/beta=1/10)
MOLECULE ID
JCGG-COM0000070 (Reaction Tree)
Skeleton
JCGG-STR002224
Product Type
beta
Yield
90%(alpha/beta=1/10)
REACTION DETAIL
Reaction Time
1.5 hours
Reaction Temp
0 degree C
Solvent
MeCN
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: The synthesis of 1,2-trans-glycoside, beta-glucopyranoside
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000132
Source
S. Hashimoto, M. Hayashi, and R. Noyori, Tetrahedron Lett., 25, 1379 (1984)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)