Reaction:JCGG-RAC0001482

JCGG ID		JCGG-RAC0001482
Submitter		The Noguchi Institute
Reaction ID		R-0000-001482
Regist Date		2012/06/21 17:10:04
REACTANT
MOLECULE ID		JCGG-COM0001667 (Reaction Tree)
	Mol	1.2 mmol
MOLECULE ID		JCGG-COM0001822 (Reaction Tree)
	Mol	1 mmol
MOLECULE ID		JCGG-COM0000099
	Reactant Type	BF3*OEt2 (in 1 mL of CH2Cl2)
	Mol	0.2 mmol
PRODUCT
MOLECULE ID		JCGG-COM0001823 (Reaction Tree)
	Yield	82%
REACTION DETAIL
Reaction Time		20 minutes + 2 hours
Reaction Temp		-30 degree C
Solvent		CH2Cl2
Comment		BF3*OEt2 was added dropwise over 20 minutes.
COMMENT
Keywords: The synthesis of 1,2-trans-glycoside, beta-glucopyranoside
REFERENCE
Reference Id		REF-0000-000073
	Source	第4版実験化学講座 (26), 丸善
Reference Id		REF-0000-000074
	Source	ISBN 4-621-03702-1
Reference Id		REF-0000-000082
	Source	R. R. Schmidt and G. Grundler, Synthesis, 1981, 885