Reaction:JCGG-RAC0001464

JCGG ID		JCGG-RAC0001464
Submitter		The Noguchi Institute
Reaction ID		R-0000-001464
Regist Date		2012/06/21 17:07:12
REACTANT
MOLECULE ID		JCGG-COM0001775 (Reaction Tree)
	Reactant Type	bromide
	Mol	6.25 mmol
MOLECULE ID		JCGG-COM0001776 (Reaction Tree)
	Reactant Type	alcohol
	Mol	5.0 mmol
MOLECULE ID		JCGG-COM0000624
	Reactant Type	AgOSO2CF3 (in 20 + 20 mL of PhCH3)
	Mol	6.25 + 2.5 mmol
MOLECULE ID		JCGG-COM0000625
	Reactant Type	s-collidine
	Mol	3.0 + 1.5 mmol
PRODUCT
MOLECULE ID		JCGG-COM0001777 (Reaction Tree)
	Yield	81%
REACTION DETAIL
Reaction Time		2 hours, 6 hours
Reaction Temp		-40 degree C, -40 degree C
Solvent		CH2Cl2, CH2Cl2
Comment		1) bromide+alcohol, MS 4A, AgOSO2CF3, s-collidine, 2) +AgOSO2CF3, s-collidine
		MS 4A was included in the solvent.
		AgOSO2CF3 and s-collidine were added twice.
COMMENT
Keywords: The synthesis of 1,2-trans-glycoside, beta-glucopyranoside
There are multiple steps in this reaction.
REFERENCE
Reference Id		REF-0000-000073
	Source	第4版実験化学講座 (26), 丸善
Reference Id		REF-0000-000074
	Source	ISBN 4-621-03702-1
Reference Id		REF-0000-000117
	Source	P. Fugedi, W. Birberg, P. J. Garegg, and A. Pilotti, Carbohydr. Res., 164, 297, (1987)