JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001458
Submitter
The Noguchi Institute
Reaction ID
R-0000-001458
Regist Date
2012/06/21 17:06:19
REACTANT
MOLECULE ID
JCGG-COM0001760 (Reaction Tree)
Skeleton
JCGG-STR032527
MOLECULE ID
JCGG-COM0001761 (Reaction Tree)
Skeleton
JCGG-STR032527
PRODUCT
MOLECULE ID
JCGG-COM0001762 (Reaction Tree)
Skeleton
JCGG-STR019472
Product Type
alpha
Yield
78%(alpha/beta=1/4.9)
MOLECULE ID
JCGG-COM0001763 (Reaction Tree)
Product Type
beta
Yield
78%(alpha/beta=1/4.9)
REACTION DETAIL
Reaction Time
48 hours
Reaction Temp
room temp
Solvent
MeCN
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: The synthesis of 1,2-cis-glycoside, beta-mannopyranoside
The reaction is the 2nd part of the sequence.
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000112
Source
V. K. Srivastava and C. Schuerch, J. Org. Chem., 46, 1121 (1981)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)