JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001453
Submitter
The Noguchi Institute
Reaction ID
R-0000-001453
Regist Date
2012/06/21 17:05:25
REACTANT
MOLECULE ID
JCGG-COM0001743 (Reaction Tree)
MOLECULE ID
JCGG-COM0001744 (Reaction Tree)
Skeleton
JCGG-STR025538
MOLECULE ID
JCGG-COM0001739
Reactant Type
Ag2SiO3
PRODUCT
MOLECULE ID
JCGG-COM0001745 (Reaction Tree)
Product Type
alpha
Yield
68%(alpha/beta=1/2.6)
MOLECULE ID
JCGG-COM0001746 (Reaction Tree)
Product Type
beta
Yield
68%(alpha/beta=1/2.6)
REACTION DETAIL
Reaction Time
NOT specified
Reaction Temp
NOT specified
Solvent
ClCH2CH2Cl
Comment
Very few were described regarding this reaction.
MS 4A was included in the solvent.
COMMENT
Keywords: The synthesis of 1,2-cis-glycoside, beta-mannopyranoside
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000108
Source
F. Yamazaki, T. Nukada, Y. Ito, S. Sato, and T. Ogawa, Tetrahedron Lett., 30, 4417 (1989); F. Yamazaki, T. Kitajima, T. Nukada, Y. Ito, and T. Ogawa, Carbohydr. Res., 201, 15 (1990)

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