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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001451 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001451
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Regist Date |
2012/06/21 17:04:49 | ||||
| REACTANT | |||||
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Reactant Type |
bromide (in 25 mL of CH2Cl2) | ||||
Mol |
8.75 mmol | ||||
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Reactant Type |
alcohol | ||||
Mol |
8.5 mmol | ||||
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Reactant Type |
Ag2SiO3 | ||||
Weight |
6.5g | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
81% | ||||
| REACTION DETAIL | |||||
Reaction Time |
20 + 30 minutes | ||||
Reaction Temp |
-20 degree C | ||||
Solvent |
CH2Cl2 | ||||
Comment |
The alcohol and Ag2SiO3 were mixed and stirred for 1 hour at room temperature before the reaction. | ||||
| The bromide was added dropwise over 20 minutes. | |||||
| COMMENT | |||||
| Keywords: The synthesis of 1,2-cis-glycoside, beta-mannopyranoside | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000073 | ||||
Source |
第4版 実験化学講座 (26), 丸善 | ||||
Reference Id |
REF-0000-000074 | ||||
Source |
ISBN 4-621-03702-1 | ||||
Reference Id |
REF-0000-000106 | ||||
Source |
H. Paulsen and O. Lockhoff, Chem. Ber., 114, 3102 (1981) | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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