JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001450
Submitter
The Noguchi Institute
Reaction ID
R-0000-001450
Regist Date
2012/06/21 17:04:37
REACTANT
MOLECULE ID
JCGG-COM0000046 (Reaction Tree)
MOLECULE ID
JCGG-COM0000071 (Reaction Tree)
Skeleton
JCGG-STR032525
MOLECULE ID
JCGG-COM0001736
Reactant Type
p-NO2C6H4SO2Cl
MOLECULE ID
JCGG-COM0000624
Reactant Type
AgOSO2CF3
PRODUCT
MOLECULE ID
JCGG-COM0000072 (Reaction Tree)
Skeleton
JCGG-STR029986
Yield
86%
REACTION DETAIL
Reaction Time
overnight
Reaction Temp
-40 to 0 degree C
Solvent
MeCONMe2, Et3N, CH2Cl2
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: The synthesis of 1,2-cis-glycoside, alpha-glucopyranoside
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000105
Source
S. Koto, N. Morishima, M. Owa, and S. Zen, Carbohydr. Res., 130, 73 (1984)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)