JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001443
Submitter
The Noguchi Institute
Reaction ID
R-0000-001443
Regist Date
2012/06/21 17:03:39
REACTANT
MOLECULE ID
JCGG-COM0001715 (Reaction Tree)
Mol
0.17 mmol
MOLECULE ID
JCGG-COM0001716 (Reaction Tree)
Skeleton
JCGG-STR031555
Mol
0.13 mmol
MOLECULE ID
JCGG-COM0000032
Reactant Type
AgClO4
Mol
0.34 mmol
MOLECULE ID
JCGG-COM0000813
Reactant Type
SnCl2
Mol
0.34 mmol
PRODUCT
MOLECULE ID
JCGG-COM0001717 (Reaction Tree)
Skeleton
JCGG-STR026896
Product Type
alpha
Yield
96%(alpha/beta=10/1)
MOLECULE ID
JCGG-COM0001718 (Reaction Tree)
Skeleton
JCGG-STR024558
Product Type
beta
Yield
96%(alpha/beta=10/1)
REACTION DETAIL
Reaction Time
4 hours
Reaction Temp
room temp
Solvent
Et2O
Comment
The reactants were mixed at -20 degree in Celsius, and gradually raised to room temperature.
MS 4A was included in the solvent.
COMMENT
Keywords: The synthesis of 1,2-cis-glycoside, alpha-glucopyranoside
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000098
Source
Y. Nakahara and T. Ogawa, Carbohydr. Res., 194, 95 (1989)

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