JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001442
Submitter
The Noguchi Institute
Reaction ID
R-0000-001442
Regist Date
2012/06/21 17:03:26
REACTANT
MOLECULE ID
JCGG-COM0001711 (Reaction Tree)
Skeleton
JCGG-STR031569
MOLECULE ID
JCGG-COM0001712 (Reaction Tree)
Skeleton
JCGG-STR032525
MOLECULE ID
JCGG-COM0000009
Reactant Type
Me3SiOSO2CF3
PRODUCT
MOLECULE ID
JCGG-COM0001713 (Reaction Tree)
Skeleton
JCGG-STR005065
Product Type
alpha
Yield
83%(alpha/beta=5/1)
MOLECULE ID
JCGG-COM0001714 (Reaction Tree)
Skeleton
JCGG-STR002224
Product Type
beta
Yield
83%(alpha/beta=5/1)
REACTION DETAIL
Reaction Time
1 hour
Reaction Temp
room temp
Solvent
Et2O
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: The synthesis of 1,2-cis-glycoside, alpha-glucopyranoside
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000097
Source
R. R. Schmidt, Angew. Chem., Int. Ed. Engl., 25, 212 (1986)

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